What is Ethylene?
Ethylene, also known by its IUPAC name ethene (C₂H₄), is the simplest alkene and a highly flammable, colorless gas with a faint sweet, musky odor. Although noncorrosive and not toxic, ethylene acts as a simple asphyxiant and can pose significant hazards; it is easily ignited, and flames may flash back to the source of a leak, while containers exposed to intense heat or fire may rupture violently. The vapors produced from boiling ethylene are lighter than air and can contribute to explosive conditions. Industrially, ethylene is a crucial organic chemical, widely used as a precursor in the production of polymers, plastics, solvents, and antifreeze. It also finds applications as an anesthetic and refrigerant. Ethylene is primarily produced through steam cracking, a petrochemical process where hydrocarbons are heated with steam at high temperatures (750–950 °C), breaking larger molecules into smaller, unsaturated compounds like ethylene.
Structure of Ethylene
- Molecular Formula: C₂H₄
- Structural Formula: H₂C=CH₂
- Bonding: Ethylene consists of two carbon atoms double-bonded to each other, with each carbon also bonded to two hydrogen atoms.
- Hybridization: Each carbon atom is sp² hybridized, forming a trigonal planar geometry.
- Bond Angle: Approximately 120° between H-C-H and H-C=C bonds.
- Pi (π) Bond: The double bond includes one sigma (σ) bond and one pi (π) bond, making ethylene reactive in polymerization and addition reactions.
Properties of Ethylene
Property | Description/Value | Units |
---|---|---|
Chemical Properties | ||
Chemical Formula | C2H4 | - |
IUPAC Name | Ethene | - |
Molecular Weight | 28.054 | g/mol |
CAS Number | 74-85-1 | - |
Hybridization | sp2 | - |
Bond Angle | ≈120 | degrees |
Physical Properties | ||
Appearance | Colorless gas | - |
Odor | Faint sweet/musky | - |
State at STP | Gas | - |
Melting Point | -169.2 | °C |
Boiling Point | -103.7 | °C |
Density (gas, 15°C) | 1.178 | kg/m³ |
Density (liquid, b.p.) | 570 | kg/m³ |
Solubility in Water | 25 | mg/L (25°C) |
Refractive Index | 1.363 | (at -100°C) |
Viscosity (gas, 25°C) | 0.0108 | cP |
Dipole Moment | 0 | D (Debye) |
Thermal Properties | ||
Critical Temperature | 9.9 | °C |
Critical Pressure | 50.4 | bar |
Critical Density | 214 | kg/m³ |
Autoignition Temperature | 490 | °C |
Flammability Limits | 3-36 | % in air |
Heat of Combustion | -1411 | kJ/mol |
Heat of Formation | 52.3 | kJ/mol |
Specific Heat Capacity (gas, 25°C) | 1.53 | kJ/(kg·K) |
Thermal Conductivity (gas, 25°C) | 0.017 | W/(m·K) |