What is Ethylene?

Ethylene, also known by its IUPAC name ethene (C₂H₄), is the simplest alkene and a highly flammable, colorless gas with a faint sweet, musky odor. Although noncorrosive and not toxic, ethylene acts as a simple asphyxiant and can pose significant hazards; it is easily ignited, and flames may flash back to the source of a leak, while containers exposed to intense heat or fire may rupture violently. The vapors produced from boiling ethylene are lighter than air and can contribute to explosive conditions. Industrially, ethylene is a crucial organic chemical, widely used as a precursor in the production of polymers, plastics, solvents, and antifreeze. It also finds applications as an anesthetic and refrigerant. Ethylene is primarily produced through steam cracking, a petrochemical process where hydrocarbons are heated with steam at high temperatures (750–950 °C), breaking larger molecules into smaller, unsaturated compounds like ethylene.

Structure of Ethylene

  • Molecular Formula: C₂H₄
  • Structural Formula: H₂C=CH₂
  • Bonding: Ethylene consists of two carbon atoms double-bonded to each other, with each carbon also bonded to two hydrogen atoms.
  • Hybridization: Each carbon atom is sp² hybridized, forming a trigonal planar geometry.
  • Bond Angle: Approximately 120° between H-C-H and H-C=C bonds.
  • Pi (π) Bond: The double bond includes one sigma (σ) bond and one pi (π) bond, making ethylene reactive in polymerization and addition reactions.
 

Properties of Ethylene

Property Description/Value Units
Chemical Properties
Chemical Formula C2H4 -
IUPAC Name Ethene -
Molecular Weight 28.054 g/mol
CAS Number 74-85-1 -
Hybridization sp2 -
Bond Angle ≈120 degrees
Physical Properties
Appearance Colorless gas -
Odor Faint sweet/musky -
State at STP Gas -
Melting Point -169.2 °C
Boiling Point -103.7 °C
Density (gas, 15°C) 1.178 kg/m³
Density (liquid, b.p.) 570 kg/m³
Solubility in Water 25 mg/L (25°C)
Refractive Index 1.363 (at -100°C)
Viscosity (gas, 25°C) 0.0108 cP
Dipole Moment 0 D (Debye)
Thermal Properties
Critical Temperature 9.9 °C
Critical Pressure 50.4 bar
Critical Density 214 kg/m³
Autoignition Temperature 490 °C
Flammability Limits 3-36 % in air
Heat of Combustion -1411 kJ/mol
Heat of Formation 52.3 kJ/mol
Specific Heat Capacity (gas, 25°C) 1.53 kJ/(kg·K)
Thermal Conductivity (gas, 25°C) 0.017 W/(m·K)

Effect of Temperature on Ethylene Density (at 50 bar)

Temperature Units:
Liquid Phase
Supercritical Phase
Critical Point (9.9°C/282.9K, 214 kg/m³)